LTE uses a diferent protocol than the UMTS/GPRS/EV-DO from openwrt.
Openwrt uses ppp protocol to connect the 3g modems, but for LTE is different. It uses CDC or NDIS connections, that have no support in openwrt yet. But the drivers exists and is possible to connect using scripts that can be started automatically.
This guy was trying to modify the protocol, but no success yet.
I succeed to connect my Huawei e3276 in NDIS mode using LTE via script, but there is no web control tool for it. the e3276 uses the usb-serial port (listed as "/dev/ttyUSB1") to send commands to the modem, the protocol used was DHCP (but the IP address was provided via the serial port, weird thing), and the adapter was "wwan0".
Further details are in this topic: https://forum.openwrt.org/viewtopic.php?id=45779